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Edexcel ·Chemistry·Cambridge AS & A Level Chemistry

Carbonyl & Carboxylic Acid Compounds & Esters

16 min read

Aldehydes and ketones and their tests, nucleophilic addition, carboxylic acids and their acidity, esters and esterification/hydrolysis, and acyl chlorides.

Aldehydes and ketones (carbonyl compounds)

Both contain the carbonyl group C=O. Aldehydes have it at the end (RCHO\text{RCHO}RCHO); ketones have it within the chain (RCOR’\text{RCOR'}RCOR’). The C=O is polar, so they undergo nucleophilic addition.

    Reduction by NaBH4\text{NaBH}_4NaBH4​: aldehyde → primary alcohol; ketone → secondary alcohol.
    Nucleophilic addition of HCN (with KCN\text{KCN}KCN/trace acid) → a hydroxynitrile (adds a C; the CN⁻ lone pair attacks the Cδ+\text{C}^{\delta+}Cδ+).

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