Bonding in alkenes, electrophilic addition reactions and their mechanism, Markovnikov's rule, and addition polymers.
Alkenes () are unsaturated hydrocarbons with a reactive C=C double bond (a σ and a π bond). The π bond is a region of high electron density, so alkenes undergo electrophilic addition.
Electrophilic addition
The π electrons attack an electrophile (electron-poor species). General mechanism (e.g. HBr + ethene):
- The C=C π electrons attack the δ+ end of HBr, forming a carbocation and a bromide ion.
- The bromide ion attacks the carbocation, forming the product.
Use curly arrows (movement of an electron pair) in the mechanism.
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